Evidence that the availability of an allylic hydrogen governs the regioselectivity of the Wacker oxidation.
نویسندگان
چکیده
The allylic hydrogen is found to have a dramatic effect on the regioselectivity of the Wacker oxidation, leading to the postulation that an agostic hydrogen or enyl (sigma + pi) complex helps to stabilise the key intermediate.
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ورودعنوان ژورنال:
- Chemical communications
دوره 18 شماره
صفحات -
تاریخ انتشار 2001